STRUCTURAL CHARACTERIZATION OF DICYANIDOBIS(N,N?-DIMETHYLTHIOUREA-kS)CADMIUM(II)

cadmium cyanide N N?-dimethylthiourea crystal structure

HETEROBIMETALLIC DIOXOMOLYBDENUM(VI) COMPLEXES DERIVED FROM BIS(2-HYDROXY-1-NAPHTHALDEHYDE)MALONOYLDIHYDRAZONE: SYNTHESIS AND CHARACTERIZATION, STRUCTURES OF TWO HYDRAZONE COMPOUNDS DERIVED FROM 4-METHYLBENZOHYDRAZIDE, ...

Ahmad 4 , H. Stoeckli- Evans 5 1Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan 2Technische Universität Chemnitz, Institut fьr Chemie, Lehrstuhl fьr Anorganische Chemie, Chemnitz, Germany 3Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia 4Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan 5 E-mail: saeed_a786@hotmail.com Institute of Physics, University of Neuchвtel, Neuchвtel, Switzerland Received February, 16, 2012 A cadmium(II) complex dicyanidobis(N,N-dimethylthiourea-S) cadmium(II) [Cd(Dmtu)2(CN)2] (1) is prepared and its structure in the solid state is determined by single crystal X-ray structural analysis. <...> The cadmium(II) ion is four-coordinate having a distorted tetrahedral geometry composed of two cyanide C atoms and two thione S atoms of N,N-dimethylthiourea (dmtu). <...> The molecular structure is stabilized by intermolecular N—HᄷN(CN) hydrogen bonding interactions that lead to a 3D network structure. <...> Except polymeric [L2CdX2] complexes, the coordination environment around Cd(II) is tetrahedral in these complexes. <...> In polymeric [L2CdX2], the structural arrangements are based on a distorted octahedral geometry [ 19—21 ]. <...> Whereas numerous adducts of cadmium halides with thiourea ligands have been structurally characterized [ 9—19, 24 ], the number of complexes defined with Cd(CN)2 is much more limited [ 8 ]. <...> We are particularly interested in studying the coordination chemistry of cyanido complexes of d10 metals such as silver(I), gold(I), and mercury(II), and in this regard we have already reported the spectroscopic and structural characterization of a number of silver(I) and gold(I) cyanide complexes of thiones [ 26—33 ]. <...> As a part of our continuing interest in the coordination chemistry of thione and cyanide ligands, we report here the spectral and structural characterization of a cadmium(II) cyanide complex of N,N-dimethylthiourea (Dmtu). <...> Cadmium chloride (CdCl2 ŒH2O) was obtained from Merck Chemical Company, Germany and N,N-dimethylthiourea (Dmtu) was purchased from Acros Organics, Belgium. <...> Complex 1 was prepared by adding 2 mmol <...>

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