STRUCTURES, PROPERTIES AND TOPOLOGIES OF TWO LAYERED COMPOUNDS BASED ON 2-CARBOXETHYL(PHENYL)PHOSPHINIC ACID

Hydrothermal syntheses of 2-carboxyethyl(phenyl)phosphinic acid (H2CEPPA) with Bi(NO3)3 and Cd(NO3)2 produce two layered complexes [Bi2(µ3-O)(СЕРРА)2]n (1) and [Cd(HCEPPA)2]n (2). Compound 1 is comprised of [Bi4(µ3-O)2(POO)4(COO)4] SBUs which grow into a double wave-like 2D layer with —CH2CH2— spacers. Compound 2 crystallizes in the orthorhombic noncentrosymmetric space group Pca21, exhibiting a double lattice-like layer.

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Тэги

crystal structure fluorescence 2-carboxyethyl(phenyl)phosphinic acid TGA topology.

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Прикладные науки. Медицина. Технология

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Hydrothermal syntheses of 2-carboxyethyl(phenyl)phosphinic acid (H2CEPPA) with Bi(NO3)3 and Cd(NO3)2 produce two layered complexes [Bi2(µ3-O)(СЕРРА)2]n (1) and [Cd(HCEPPA)2]n (2). <...> Compound 1 is comprised of [Bi4(µ3-O)2(POO)4(COO)4] SBUs which grow into a double wave-like 2D layer with —CH2CH2— spacers. <...> Compound 2 crystallizes in the orthorhombic noncentrosymmetric space group Pca21, exhibiting a double lattice-like layer.! <...> Hydrothermal syntheses of 2-carboxyethyl(phenyl)phosphinic acid (H2CEPPA) with Bi(NO3)3 and Cd(NO3)2 produce two layered complexes [Bi2(µ3-O)(СЕРРА)2]n (1) and [Cd(HCEPPA)2]n (2). <...> Compound 1 is comprised of [Bi4(µ3-O)2(POO)4(COO)4] SBUs which grow into a double wave-like 2D layer with —CH2CH2— spacers. <...> Compound 2 crystallizes in the orthorhombic noncentrosymmetric space group Pca21, exhibiting a double lattice-like layer.! <...>

** - вычисляется автоматически, возможны погрешности

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STRUCTURES, PROPERTIES AND TOPOLOGIES OF TWO LAYERED COMPOUNDS BASED ON 2-CARBOXETHYL(PHENYL)PHOSPHINIC ACID

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